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Title: Synthesis and characterization of terpolymer of α-terpineol, styrene and methylmethacrylate: A kinetic study
Authors: Yadav, Sarika
Srivastava, A K
Issue Date: Oct-2004
Publisher: NISCAIR-CSIR, India
IPC Code: Int.Cl.7 C08F2/04
Abstract: Synthesis of a series of functional terpolymers, consisting of two electron donating monomers viz.. α-terpineol and styrene with one electron accepting monomer i.e. methylmethacrylate, using benzoylperoxide as radical initiator and xylene as diluent at 80°C for 2 h has been studied. The system follows ideal kinetics with an overall activation energy 23 kJ/mol. The formation of the terpolymer is confirmed by 1H NMR and FTIR spectrum. The reactivity ratios calculated using Kelen-Tudos method are r1 (MMA) = 0.85 and r2 (styrene +α-terpineol) = 0.17.
Page(s): 2094-2097
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.43A(10) [October 2004]

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