Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/20412
Title: Synthesis and characterization of organotin(IV) complexes of p-phenylphenol
Authors: Sharma, Neeraj
Pathania, S S
Archana
Bhatt, S S
Chaudhry, S C
Issue Date: Aug-2004
Publisher: NISCAIR-CSIR, India
IPC Code: Int. Cl.7 C07F 7/22
Abstract: The di-and tri-organotin(IV) complexes with the composition R2SnCl2-n(OC6H4Ph-p)n and (C6H5)3Sn(OC6H4Ph-p) (R = n-C4H9 and Me; n = 1 and 2) have been synthesized by the reaction of dialkyl and triphenyltin(IV) chlorides with p-phenyl phenol in the presence of diethylamine in diethylether at room temperature. The complexes have been characterized by their analytical data and IR and 1H NMR spectra. Thermal behaviour of the complexes has been studied by TGA/DTA methods. Lewis acid character of the complexes has been established by reacting them with nitrogenous bases such as 2,2ʹ-bipyridyl,1,10- phenanthroline and 2,2'- dipyridylamine.
Page(s): 1672-1675
URI: http://hdl.handle.net/123456789/20412
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.43A(08) [August 2004]

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