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Title: Thermal decomposition kinetics of some aniline complexes of zinc group metals
Authors: Sikha, T S
Indrasenan, P
Issue Date: Jul-2004
Publisher: NISCAIR-CSIR, India
IPC Code: Int. C17. C 08G 59/70
Abstract: The kinetics and mechanism of thermal decomposition of aniline complexes of zinc group metals have been studied using non-isothermal thermogravimetry. Kinetic parameters have been calculated for each of the decomposition stages using the Coats-Redfern equation. The mechanisms of the reactions have also been found out, and the rate controlling processes are found to be either random nucleation with the formation of one nucleus on each particle (Mampel equation) or phase boundary reaction with cylindrical symmetry or spherical symmetry.
Page(s): 1393-1402
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections: IJC-A Vol.43A(07) [July 2004]

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