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Title: Synthesis, characterization and electrochemistry of [Ru(L )(2,2' -bpy)Cl2]: (L= 4 aryl substituted thiosemicarbazide; bpy = bipyridine)
Authors: Maji, Milan
Sengupta, Parbati
Dinda, Rupam
Issue Date: Apr-2004
Publisher: NISCAIR-CSIR, India
IPC Code: Inl. Cl. 7 C01G 55/00
Abstract: A series of ruthenium (II) complexes of general formula Ru(L)(bipy)Cl2 with different thiosemicarbazides (L) which ligated to the metal ion in the thione form have been synthesized by reacting Ru(bipy)Cl4 with the corresponding ligands in methanol. One bipyridine molecule and two chloride ligands complete the hexacoordination. The compounds have been characterised by elemental analysis, magnetic moment measurement and by different spectroscopic methods. The redox behaviour of the compounds has been explored by cyclic voltammetry.
Page(s): 790-792
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.43A(04) [April 2004]

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