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|Title:||Synthesis and characterization of 2-tert.butyl phenoxotitanium(IV) complexes|
|Authors:||Bhatt, S S|
Chaudhry, S C
|Abstract:||Complexes of composition TiCl4-n(OC6H4-But-2)n (where n = 1 to 4 and OAr = OC6H4- But-2) have been prepared by the reaction of titanium(IV) chloride with Me3SiOAr in predetermined molar ratios in carbon tetrachloride/toluene as solvent These complexes have been characterized by elemental , IR, 1H NMR and TG analysis and molecular weight determinations. Lewis acid character of the complexes has also been established by isolating adducts with some monodentate aliphatic amines and bidentate aromatic amines.|
|Appears in Collections:|| IJC-A Vol.43A(01) [January 2004]|
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