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Title: Kinetics and mechanism of oxidation of substituted benzyl alcohol by polymer supported oxidizing agent
Authors: Jawanjal, A L
Hilage, N P
Issue Date: Sep-2005
Publisher: NISCAIR-CSIR, India
IPC Code: Int. Cl.7 C07B33/00
Abstract: The kinetics of oxidation of monosubstituted benzyl alcohol with polymer supported chromic acid in 1:4 dioxane has been studied. The reaction is found to be of zero order each in [alcohol] and [oxidant). The effect of substituent on the rate of oxidation and the thermodynamic parameters are evaluated. The reaction products have been isolated and characterised by their derivatives. A probable mechanism of oxidation is proposed.
Page(s): 1827-1830
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.44A(09) [September 2005]

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