|
NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR) >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.47B [2008] >
IJC-B Vol.47B(08) [August 2008] >
| Title: | Electrochemical nuclear acetamidation of aromatic compounds at the platinum anode |
| Authors: | Sharma, Laxmi Kant
Kumar, Sanjeev ,
Yadav, Pragati
Singh, R K P |
| Keywords: | Electrochemical oxidation
Controlled potential electrolysis
Platinum electrode
Solvent extraction
Green chemistry |
| Issue Date: | Aug-2008 |
| Publisher: | CSIR |
| Abstract: | The electrochemical nuclear acetamidation of aromatic compounds ethylbenzoate, acetophenone, benzoic acid and benzene have been carried out at platinum anode under the process of nuclear oxidation. The removal of electrons from the aromatic π-electron system is achieved by the electrochemical oxidation. The electrolysis is carried out at the constant anode potential in an electrolytic cell assembly containing reaction mixture and electrodes. The products 4-acetamidoethylbenzoate, 4-acetamidoacetophenone, 4-acetamidobenzoic acid and N-phenylacetamide formed during the electrolysis are reported here. |
| Page(s): | 1277-1280 |
| ISSN: | 0376-4699 |
| Source: | IJC-B Vol.47B(08) [August 2008]
|
|
