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|Title:||Synthesis of poly(1,3-diisopropenylbenzene peroxide)|
Sathyanarayana, D N
|Abstract:||Poly(1,3-diisopropenylbenzene peroxide) (PDIPBP) has been prepared from 1,3-diisopropenylbenzene by free-radical-initiated oxidative polymerization. The presence of peroxide group (-O-O-) in the polymer backbone has been confirmed by differential scanning calorimetry (DSC) and FTIR spectroscopy. Thermal degradation studies using DSC have revealed that PDIPBP degrades highly exothermically and the measured heat of degradation (-295.4 cal g-1) is slightly higher than that reported earlier for vinyl polyperoxides.|
|Appears in Collections:||IJC-A Vol.40A(09) [September 2001]|
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