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Title: One-dimensional chain crown ether complex Synthesis and crystal structure of novel complex: {[Na(18C6)] [Na(18C6)(H2O)]} [Cu(mnt)2]
Authors: Dou, Jianmin
Li, Dacheng
Sun, Dezhi
Liu, Ying
Xu, Liqiang
Bi, Wenhua
Zheng, Peiju
Issue Date: Aug-2001
Publisher: NISCAIR-CSIR, India
Abstract: The reaction of 18-crown-6 with Na2Cu(mnt)2 (mnt = 1 ,2-dicyanoethene-1 ,2-dithiolate, C2S2(CN)22-) gives the novel complex, {[Na(l8C6)] [Na(18C6) (H2O)]} [Cu(mnt)2]. The complex has been characterized by elemental analysis, IR spectrum and X-ray diffraction analysis. The complex displays a one-dimensional infinite chain of [Na(18C6)]+ complex cations and [Cu(mnt)22-] complex anion bridged by Na-N interactions between adjacent [Na(18C6)]+ units.
Page(s): 878-879
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.40A(08) [August 2001]

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