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Title: Synthesis, reactions, and spectral [NMR(1H,13C, and 29Si), IR] studies of organosilicon aryloxides
Authors: Mishra, Shashank
Singh, Anirudh
Issue Date: Jul-2001
Publisher: NISCAIR-CSIR, India
Abstract: Organosilicon aryloxides of the types Me3Si(OAr) and MeSi(OAr)3 (Ar = C6H4Bus -2; C6H3Me-2-Pr1-5; C6H3Me-5-Prl-2) have been prepared, respectively, from reactions of appropriate phenols with Me3SiCl or MeSiCl3 in benzene using Et3N as a base. Reactions of Me3Si(OAr) with TiCl4 in 1:1 and 2: 1 molar ratios in benzene afford derivatives TiCl3(OAr) and TiCl2(OAr)2, respectively. All these new derivatives have been characterized by elemental analyses, spectroscopic [IR, NMR (1H, 13C, and 29Si)] studies, as well as by molecular weight measurements.
Page(s): 772-774
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.40A(07) [July 2001]

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