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Title: Reactivity studies of (η6-p-cymene)ruthenium complexes with 4,4ʹ -bipyridine and imidazole ligands
Authors: Rao, K Mohan
Sarkhel, Prashanta
Issue Date: Jul-2001
Publisher: NISCAIR-CSIR, India
Abstract: Reactions of [(η6-p-cymene)RuCl2]2, (a), [(η6-p-cymene) Ru(EPh3)Cl2] {E = P (b) or As (c)} with 4,4ʹ-bipyridine yielded bridged complexes of the type [(η6-p-cymene)RuCl2-μ-4,4ʹ-bipy-Cl2Ru(η6-p-cymene)] (1) and [(η6-p-cymene) Ru(EPh3)- μ-4,4ʹ-bipy -Cl(EPh3)Ru(η6-p-cymene)]  {E=P, (2); As, (3)} respectively. Complex (b) with imidazole in the presence of NaBF4 in methanol gave compound of the type [(η6-p-cymene) Ru(PPh3)(im)Cl] BF4 (4) (im = imidazole). These complexes have been characterized with various spectroscopic techniques.
Page(s): 760-762
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.40A(07) [July 2001]

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