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Title: Kinetics and mechanism of silver (I) catalyzed oxidation of 1,3-propanediol by peroxodiphosphate in acetate buffers
Authors: Singh, G
Bansal, Savita
Gupta, Divya
Sharma, Indu
Khandelwal, C L
Sharma, P D
Issue Date: Jul-2001
Publisher: NISCAIR-CSIR, India
Abstract: The kinetics of silver (I) catalysed oxidation of 1,3-propanediol by peroxodiphosphate (pdp) has been studied in acetate buffers. 3-Hydroxypropanal has been identified spectrally to be the oxidation product of 1,3-propanediol. However, the rate is independent of diol concentration but first order each in the catalyst and oxidant. Rate is significantly rewrded by acetate ions. The kinetics of the reaction account for the rate law. . .
Page(s): 714-719
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.40A(07) [July 2001]

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