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Title: Kinetics of condensation of aryl isothiocyanates with aryl amines
Authors: Pathrikar, Late G Y
Bondge, S P
Burungale, A S
Bhingolikar, V E
Ingle, R D
Mane, R A
Issue Date: Dec-2002
Publisher: NISCAIR-CSIR, India
Abstract: The kinetics of condensation of aryl isothiocyanates with aryl amines in non-aqueous medium have been investigated. The condensation reaction is first order each in [amines] and [isothiocynates]. The effect of substituents on the rate of condensation and the thermodynamic parameters are evaluated. The reaction products have been isolated and characterized as asymmetric thiocarbamides and a probable mechanism of the condensation proposed.
Page(s): 2518-2521
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.41A(12) [December 2002]

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