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|Title:||A new decavanadate salt incorporating both inorganic and organic cations|
|Abstract:||The title salt, [Cs2(H2O)2 (tea)2 H2 V10 O28] has been isolated by reacting a solution of V2O5 in aqueous H2O2 with [tea][Cl] and CsCl (tea+ is triethanolammonium cation). The structure of the salt consists of an unusual three-dimensional array of centrosymmetric H2 V10 O284- units (protonation sites consistent with bond valence sums) strongly interlinked by cesium ions which are chelated by the tea+ ligand.|
|Appears in Collections:||IJC-A Vol.41A(12) [December 2002]|
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