Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/18336
Title: Synthesis and characterization of complex [Mn(η1-pyS)( dien)(CO)3] by the reaction of [Mn2(μ-PyS)2(CO)6] (pySH=pyridine-2-thiol) and diethylenetriamine (dien)
Authors: Ara, Gulsan
Kabir, Shariff E
Kundu, Kalipada
Issue Date: Aug-2002
Publisher: NISCAIR-CSIR, India
Abstract: The dimeric complex [Mn2(μ-PyS)2(CO)6] (1) reacts with 2 molar equivalents of diethylenetriamine (dien) to give the monomeric complex [Mn(η1-pyS)( dien)(CO)3]  (2) in which the pyridine-2-thiolato group coordinates to manganese through the S-atom as a two-electron donor ligand. The complex has been characterized by elemental analysis and IR, PMR and mass spectroscopy.
Page(s): 1619-1620
URI: http://hdl.handle.net/123456789/18336
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.41A(08) [August 2002]

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