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|Title:||Synthesis and crystal structure of two dimensional network DB18-C-6 complex: [Na(DB 18-C-6)]2[Pt(SCN)6]|
|Abstract:||A novel dibenzo-18-crown-6 (DB18-C-6) complex [Na(DB18-C-6)]2[Pt(SCN)6] (1) has been synthesized and characterized by elemental analysis, IR spectrum and X-ray diffraction analysis. The complex belongs to triclinic. space group P-1 with cell dimensions: a = 1.2500(3), b = 1.2825(3), c = 1.9342(4) nm, α =106.82(3) , β= 102.51(3),γ = 103.04(3)°, V = 2.7562nm3, Z=2, Dcalcd = 1.579 g/cm3, F(000) = 1316, R1 = 0.0364, wR2 = 0.0771. The complex shows a two-dimensional network structure of [Na(DB18-C-6)+ complex cations and [Pt(SCN)6]2- complex anion bridged by Na-N interactions between adjacent [Na(DB 18-C-6)+ and [pt(SCN)6]2- units.|
|Appears in Collections:||IJC-A Vol.41A(07) [July 2002]|
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