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Title: Novel synthesis of allyl and cyclopropylcarbinyl thiocyanates by the reaction of organocobaloximes with thiocyanogen
Authors: Gupta, B D
Mandal, Debprasad
Dixit, Vandana
Issue Date: May-2002
Publisher: NISCAIR-CSIR, India
Abstract: Thioeyanogen reacts in aprotic solvents with allyl and but-3- enyl cobaloximes to give moderate yields of allyl and cyclopropylcarbinyl thiocyanates. Using this method highly unstable allyl thiocyanates may be prepared in situ at low temperature. Their rearrangement to isothiocyanates is observed at sub-zero temperatures.
Page(s): 970-972
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.41A(05) [May 2002]

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