Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/18181
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dc.contributor.authorGoyal, Rajendra N-
dc.contributor.authorKumar, Anil-
dc.contributor.authorGupta, Priyanka-
dc.date.accessioned2013-05-15T10:52:17Z-
dc.date.available2013-05-15T10:52:17Z-
dc.date.issued2003-04-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.identifier.urihttp://hdl.handle.net/123456789/18181-
dc.description719-726en_US
dc.description.abstractThe electrochemically driven and persulphate-mediated oxidation of indole-3 ethanol has been studied in phosphate buffers. The electrochemical oxidation is carried out at PGE and a well-defined peak is noticed. The studies reveal that no UV/ vis - absorbing intermediate is generated during electrooxidation of indole-3 -ethanol (I). On the other hand, oxidation by persulphate follows pseudo-first-order kinetics having first-order with respect to substrate. This reaction takes place with a second-order rate constant of (0.25 ± 0.01) dm3 mol-1 S-1 .The redox mechanisms of electrochemical as well as chemical oxidation have been suggested and in both the oxidations the major product of oxidation is found as hydroxy dimer (VII).en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rightsCC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.42A(04) [April 2003]en_US
dc.titleElectrochemical and persulphate mediated oxidation of indole-3-ethanolen_US
dc.typeArticleen_US
Appears in Collections:IJC-A Vol.42A(04) [April 2003]

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