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dc.contributor.authorSuja, N R-
dc.contributor.authorSridevi, N-
dc.contributor.authorYusuff, K K Mohammed-
dc.identifier.issn0975-0975(Online); 0376-4710(Print)-
dc.description.abstractThe kinetics and mechanism of the reaction between ferricytochrome C and vanadate has been investigated spectrophotometrically employing [vanadate]˃˃ [ferricytochrome C]. The reaction exhibits first order each in [ferricytochrome C] and [vanadate ion]. The pseudo-first order rate constant decreases with an increase in ionic strength and increases with an increase in pH in the range 7 to 8. A suitable mechanism has been proposed on the basis of these results. The deprotonation constant for ferricytochrome C and the second order rate constant for the present reaction at 30oC have been determined from this study as (1.01 ±0.05)×10-7 mol dm-3 and 95.2±0.5 dm3 mol-1 s-1 respectively.en_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rightsCC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJC-A Vol.43A(09) [September 2004]en_US
dc.titleKinetics and mechanism of reduction of ferricytochrome C by vanadate in phosphate buffersen_US
Appears in Collections:IJC-A Vol.43A(09) [September 2004]

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