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Title: Kinetics of reactions of o-(2,4-dinitrophenyl)indanone oxime with cyclohexylamine, piperidine and ethanolamine in acetonitrile
Authors: Bhattacharjee, Gurudas
Singh, Ashok Kumar
Singh, Rupam
Gairola, Priti
Issue Date: May-2004
Publisher: NISCAIR-CSIR, India
IPC Code: Int. Cl.7 C07C 251/32
Abstract: Effect of nucleophile on the reactions of o-(2,4-dinitrophenyl) indanone oxime (DNPIO) has been studied with cyclohexylamine (CHA), ethanolamine (ETA) and piperidine (PIP) in acetonitrile at 35±0.1oC. Reactions of DNPIO with CHA and ETA are kinetically of second order. However, the reactions with PIP are wholly base catalyzed and a third order dependence on PIP has been observed.
Page(s): 1051-1055
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.43A(05) [May 2004]

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