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Title: Synthesis and characterisation of iron(III) complexes of 1,2-dihydro-l-phenyl-2,3- dimethyl-4-[2',4'-pentanedione-3'- hydrazono]pyrazol-5-one
Authors: Ravindran, Reena
Issue Date: Jun-2004
Publisher: NISCAIR-CSIR, India
IPC Code: C 01 G 49/00
Abstract: A novel heterocyclic ligand , 1,2-d ihydro-1-phenyl-2,3-dimethyl-4-[2',4' -pentanedione-3' -hydrazono]pyrazol-5-one,[AAPAAC], and its complexes with iron(III) in the presence of chloride, bromide, nitrate and perchlorate anions, have been synthesised and characterised using elemental analyses, conductance measurements, magnetic susceptibility and infrared, electronic and Mossbauer spectral studies. The ligand shows neutral bidentate and tri dentate behaviour in the complexes. Spectral studies confirm an octahedral geometry around iron(III) in all the complexes.
Page(s): 1245-1248
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.43A(06) [June 2004]

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