Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/18113
Title: Synthesis and characterization of some homo/hetero binuclear hydrido carbonyl ruthenium(II) polypyridyl complexes
Authors: Chandra, Manish
Sahay, Abhaya Nand
Pandey, Daya Shankar
Issue Date: Feb-2004
Publisher: NISCAIR-CSIR, India
Abstract: Mononuclear hydri do carbonyl complex [RuH(CO)(PPh3)2-(η2-tptz)]BF4 (tptz = 2,4,6-tris-(2' -pyridyl)- 1,3,5-triazine) has been used as a building block in the synthesis of homo/hetero binuclear complexes. The complex [RuH(CO)(PPh3)2(tptz)]BF4 behaves as a potential metallo- ligand. Its reaction with different molecules ranging from K2PtCl4, [PdCl2(PhCN]2, chloro- bridged dimeric arene ruthenium complexes  [{Ru(η6-arene)(µ-Cl)CI}2] (arene = p-cymene or benzene), [{Rh(η5-C5Me5) (µ-Cl)Cl}2] and [Rh(COD)(µ-Cl)]2 (COD) = 1.5 cyclooctadiene) leads to the formation of binuclear complexes. The homo and hetero binuclear tptz bridged complexes complex [RuH(CO)(PPh3)2(µ-tptz)PdCl2]BF4, [RuH(CO)(PPh3)2(µ-tptz)PdCl2]BF4, [RuH(CO)(PPh3)2(µ-tptz)-(η6-C10 H14)RuCl(BF4)2, [RuH(CO)(PPh3)2(µ-tptz)(η6-C6 Me6)-RuCl(BF4)2, [RuH(CO)(PPh3)2(µ-tptz)(η2-COD)RH](BF4)and [RuH(CO)(PPh3)2(µ-tptz)(η5-C5Me5)Cl](BF4)2 have been synthesized and characterized using IR, NMR, ESMS and FAB mass spectra.
Page(s): 323-328
URI: http://hdl.handle.net/123456789/18113
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.43A(02) [February 2004]

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