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Title: Mixed ligand triphenylphosphine/arsine Schiff base complexes of ruthenium(II) and their catalytic activities towards oxidation of alcohols
Authors: Viswanathamurthi, P
Geetha, A
Karvembu, R
Natarajan, K
Issue Date: Jan-2005
Publisher: NISCAIR-CSIR, India
IPC Code: Int Cl.7 C07F 15/00; C07C 251/02
Abstract: Mixed ligand ruthenium(II) complexes [Ru(CO)(Y)(L)], where Y = PPh3, AsPh3, pyridine (py) or piperidine (pip) and H2L = Schiff bases derived from the condensation of o-aminophenol, o-aminothiophenol and anthranillic acid with acetyl acetone in 2:1 molar ratio, obtained from the reactions of [RuHX(CO)(EPh3)2(Y)] (X = H or Cl ; E = P or As) with H2L, have been found to show catalytic activity in the oxidation of alcohols to aldehydes.
Page(s): 90-93
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.44A(01) [January 2005]

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