Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/17957
Title: Binuclear and tetranuclear dioxouranium(VI), zinc(II) and copper(II) complexes derived from bis(2-hydroxy -1-naphthaldehyde )malonoyldihydrazone
Authors: Lal, R A
Basumatary, D
Chakraborti, J
Bhaumik, S
Kumar, A
Issue Date: Mar-2006
Publisher: NISCAIR-CSIR, India
IPC Code: Int. Cl.8 C07F1/08; C07F3/06: C07F5/00
Abstract: The complexes [(UO2)2(CH2L)(H2O)4] (1), [M4(CH2L)2(H2O)4].4H2O [M= Zn (2) and Cu (3)], (M1)2[(UO2F)2(CH2L)(H2O)2] [M = K (4), Na (6)], M1[(UO2)2(CH2L) (OAc)(H2O)2 ] [M = K (5), Na (7)], K 4[(MF)2(CH2L)2].4H2 [M = Zn (8) and Cu (9)] have been synthesized from reaction of appropriate metal salts with bis(2-hydroxy-1-naphthaldehyde)malonoyl-dihydrazone (CH2LH4) in different experimental conditions in ethanol/methanol media. The complexes have been characterized by elemental analyses, molecular weight, molar conductance, magnetic moment and ESR data. The structural assessment of the complexes has been carried out on the basis of electronic, infrared, 1H NMR and 13C NMR spectral studies.
Page(s): 619-628
URI: http://hdl.handle.net/123456789/17957
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections: IJC-A Vol.45A(03) [March 2006]

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