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|Title:||Synthetic, spectroscopic and electrochemical behaviour of biomimetic copper(II) complex with CuN4 chromophore|
|Authors:||Patel, R N|
Gundla, V L N
|IPC Code:||Int.Cl.8 C07F1/08|
|Abstract:||X-band electron paramagnetic resonance, electronic spectra and cyclic voltammetry of [Cu(Phen)2 ] (BF4)2 where phen = 1.10-phenanthroline, is reported here. The solution co-ordination structure of the title complex has been ascertained. The geometry around the copper(II) is distorted tetrahedral (due to tetrahedral distortion from planar) established by high g‖, low A‖ and high g‖/A‖ value and also by Symons plot. Superoxide dismutase activity of the compound has also been measured. The complex catalyzes the dismutation of O2- with an IC50 value of 3.5μ mol dm-3.|
|Appears in Collections:|| IJC-A Vol.45A(03) [March 2006]|
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