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Title: Synthetic, spectroscopic and electrochemical behaviour of biomimetic copper(II) complex with CuN4 chromophore
Authors: Patel, R N
Singh, Nripendra
Gundla, V L N
Issue Date: Mar-2006
Publisher: NISCAIR-CSIR, India
IPC Code: Int.Cl.8 C07F1/08
Abstract: X-band electron paramagnetic resonance, electronic spectra and cyclic voltammetry of [Cu(Phen)2 ] (BF4)2 where phen = 1.10-phenanthroline, is reported here. The solution co-ordination structure of the title complex has been ascertained. The geometry around the copper(II) is distorted tetrahedral (due to tetrahedral distortion from planar) established by high g, low A and high g/A value and also by Symons plot. Superoxide dismutase activity of the compound has also been measured. The complex catalyzes the dismutation of O2- with an IC50 value of 3.5μ mol dm-3.
Page(s): 614-618
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections: IJC-A Vol.45A(03) [March 2006]

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