Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/17863
Title: Aroma Chemicals by Direct Hydration/Etherification of Olefins: An Industrial Approach
Authors: Rao, L Jagan Mohan
Nagarajan, S
Gurudutt, K N
Issue Date: Sep-1999
Publisher: NISCAIR-CSIR, India
Abstract: α-Terpineol and dimethyl phenyl carbinol are prepared in excellent yields (85 per cent) by contacting an azeotropic mixture of the corresponding olefins, limonene or α-pinene and α-methylstyrene, with a strong cation exchange resin (H+ form). The corresponding methyl and ethyl ethers are prepared likewise by replacing water in the reaction mixture with methanol and ethanol respectively. While the methyl ethers are obtained in 75-80 per cent yield, the ethyl ethers are accompanied by the corresponding alcohols in equal proportion, in overall yield of 60-75 per cent.
Page(s): 692-693
URI: http://hdl.handle.net/123456789/17863
ISSN: 0975-1084 (Online); 0022-4456 (Print)
Appears in Collections:JSIR Vol.58(09) [September 1999]

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