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|Title:||Synthesis and tandem free-radical cyc1ization of dimethyl (2E,6E)-3-oxo-6, 10-dimethyl- 6, 10-dodecadiendioate with Mn(III) acetate|
|Authors:||Petrovic, Zorica D|
|Abstract:||The synthesis and tandem free- radical cyclization of dimethyl (2E,6E)-3-oxo-6, 10-dimethyl-6,10-dodecadiendioate 1 with Mn(OAc)3 are described. The unsaturated β-ketodiester 1 has been prepared from geraniol in six steps and then subjected to the reaction with Mn(OAc)3 giving the bicyclo compounds 10 and 11 in 35% and 45% yields, respectively. The reaction has been carried out under mild conditions and can be very useful method for the synthesis of the desired bicyclo compounds.|
|Appears in Collections:||IJC-B Vol.38B(12) December 1999]|
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