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|Title:||Selective conversion of nitriles to amides by Amberlyst A-26 supported hydroperoxide|
|Authors:||Lakouraj, M Mansour|
|Abstract:||A mild, efficient and selective conversion of nitriles to amides is achieved by employing Amberlyst A-26 supported hydroperoxide, which is prepared in situ from hydrogen peroxide and Amberlyst A-26 (OH- form). Nitriles and dinitriles are transformed to their corresponding amides and diamides, respectively. Reactions proceed within 0.5-5 hr upon addition of a catalytic amount of Amberlyst A 26(OH-) to a methanolic solution of nitrile and hydrogen peroxide (35%), at room temperature.|
|Appears in Collections:||IJC-B Vol.38B(08) [August 1999]|
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