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Title: Chemoselective electrooxidation of (E)-1- phenyl-2- (phenylthio)ethylene and 1-phenyl-2-(phenylthio )acetylene
Authors: Ramalingam, S
Perumal, S
Selvaraj, S
Sivasubramanian, S
Issue Date: Apr-1999
Publisher: NISCAIR-CSIR, India
Abstract: Electrooxidation of (E)-1-phenyl-2-(phenylthio)ethylene and 1- phenyl-2-(phenylthio)acetylene on glassy carbon electrode in aceto nitrile medium results in the formation of the  corresponding sulphones chemoselectively leaving the unsaturated linkages intact. These results are in contrast to the electrooxidation at platinum electrode wherein the scission of the C-S bond of these sulphides also occurs affording different products.
Page(s): 466-469
Appears in Collections:IJC-B Vol.38B(04) [April 1999]

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