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Title: Bis(1-benzyl-4-aza-1-azonia-bicyclo[2.2.2]octane) persulfate: A mild and efficient oxidant for cleavage of oxime double bonds under anhydrous conditions
Authors: Hajipour, A R
Mohammadpoor -Baltork, I
Kianfar, G
Issue Date: Feb-1999
Publisher: NISCAIR-CSIR, India
Abstract: Bis( 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane)persulfate (BAABCPS) 1 readily prepared as orange solid from commercially available 1,4-diazabicyclo[2.2.2]octane (DABCO) and potassium persulfate, converts oximes and a-sulfinyl oximes to the corresponding carbonyl compounds and β-keto sulfoxides respectively, the yields and enantiomeric purity are excellent.
Page(s): 221-224
Appears in Collections:IJC-B Vol.38B(02) [February 1999]

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