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|Title:||Effect of oxidants on olefin epoxidation catalyzed by a new nickel(II)-schiff base complex|
|Abstract:||A new schiff base complex of nickel(II), NiL ( where H2L= N-(2- hydroxyphenyl) salicyldiimine} has been prepared in good yield by direct interaction of schiff base ligand, H2L and NiCI2 and characterized by physico-chemical analysis. Efficiency of the NiL complex towards catalysing epoxidation of olefins in presence of various oxidants vi z., NaOCI , KHSO5, H2O2 ,pyridine N-oxide (PyO), t-BuOOH, etc. , has been examined and it is found that the NiL complex can effectively catalyze the epoxidation of olefins in presence of NaOCI and KHSO5.|
|Appears in Collections:||IJC-A Vol.38A(11) [November 1999]|
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