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Title: Synthesis of some manganese(O) cyanonitrosyl derivatives containing heterocyclic nitrogen donors
Authors: Maurya, R C
Pillai, V
Singh, T
Issue Date: Aug-1999
Publisher: NISCAIR-CSIR, India
Abstract: Novel mixed -ligand cyanonitrosyl  complexes  of Mn(O), obtained from the interaction of tetracyanodinitrosylmagante(O) anion, [Mn(NO)2(CN) 4]2with 2-hydroxymethylpyridine (2-HMP), 3-hydroxymethylpyridine (3-HMP), 2—aminopyridine  (2- AP), 2-(2' -aminoethyl)pyriidine(2 -AEP), quinaldic acid (QD), nicotinic acid (NA) and  methyl nicotinate (MNIC) are described . The products have  the general formula [Mn(NO)2(CN)2(L)2]  (where L-L=QD, NA, 2-AEP, 2-AP or MNIC) . Octahedral structures have been suggested for these complexes. Mn(0) has a low-spin {Mn(NO)2}7 electron configuration1 in these complexes.
Page(s): 829-832
Appears in Collections:IJC-A Vol.38A(08) [August 1999]

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