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Title: Kinetics and mechanism of the vapour phase ammoximation of cyclohexanone by nitric oxide and ammonia over Al2O3.SiO2 catalyst
Authors: Prasad, R
Vashisht, Seema
Issue Date: May-1999
Publisher: NISCAIR-CSIR, India
Abstract: The kinetics of ammoximation of cyclohexanone by nitric oxide and ammonia, in vapour phase have been investigated over Al2O3.SiO2  catalyst in a differential flow reactor between 150 and 250°C. The rate equation r = k1 pc pa has been deduced which represents the data most satisfactorily for the conversion of cyclohexanone to caprolactam. A tentative reaction mechanism has been proposed.
Page(s): 446-452
Appears in Collections:IJC-A Vol.38A(05) [May 1999]

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