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|Title:||Synthesis, magnetic and spectral studies of Co(II) picrate complexes with heterocyclic nitrogen donors|
|Authors:||Maurya, R C|
|Abstract:||New mixed-ligand picrate complexes of cobalt(II), formed by interaction of cobalt(II) picrate with 2-aminobenzothiazole (ABZT), 2-(2'-aminophenyl) benzothiazole (2 '-AMPHBZT) , 2-(3'aminophenyl) benzothiazole(3'-AMPHBZT), bipyridyl(Bipy), o- phenonthroline (Phen ), and 2 ,6- bis(benzimidazole-2'-yl) pyridine(BBZLY) are described. The complexes have been characterised by elemental analyses, molar conductances, magnetic and decomposition temperature measurements, electron spin resonance, infrared and electronic spectral studies. They have the composition [Co(PA)2(L-L) 2], where L - L= ABZT, 2'-AMPHBZT, 3'AMPHBZT, Bipy, Phen or BBZLY. A trans octahedral structure has been tentatively proposed for these complexes.|
|Appears in Collections:||IJC-A Vol.38A(05) [May 1999]|
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