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Title: Cleavage of Co-C bond in allyl cobaloximes with arenesulphenyl chloride
Authors: Gupta, B D
Dixit, Vandana
Singh, Veena
Kanth, V Vijai
Issue Date: Aug-2000
Publisher: NISCAIR-CSIR, India
Abstract: Arenesulphenyl chlorides (ArSCI; Ar = Ph, C6Cl5, 2,4(N02)2 C6H3) are reacted with allylcobaloximes, RCo(dmgH)2Py (R= allyl), under thermal and photochemical conditions to obtain the corresponding sulphides as the major organic products.-Pinenyl cobaloxime forms the ring opened product as well. The homolytic as well as heterolytic cleavage of the Co-C bond is considered.
Page(s): 830-834
Appears in Collections:IJC-A Vol.39A(08) [August 2000]

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