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Title: A single step synthesis of some cyanonitrosyl {CrNO}5 complexes of chromium(I) involving multi-functional ligands directly from chromate(VI) in aqueous-aerobic medium
Authors: Maurya, R C
Thakur, S K
Batalia, S
Issue Date: Aug-2000
Publisher: NISCAIR-CSIR, India
Abstract: Novel mixed-ligand cyanonitrosyl complexes of chromium(I), formed by interaction of tetracyanonitrosylchromate(I) anion. [Cr(NO)(CN)4]2 with 8-hydroxyquinoline (8-HQ), benzothiazole (BZT), imidazole (IDL), methyl benzothiazole (MBZT) and pheniramine maleate (PHM) are described. The resulting mixed-ligand complexes, which have been characterized by  elemental analyses, molar conductances, magnetic measurements, electron spin resonance, infrared and electronic spectral studies, have the compositions [Cr(NO)(CN)2(L)2 (H2O)], where L= BZT. MBZT or IDL and [Cr(NO)(CN)2 (L-L)(H2O)] where L-L = 8-HQ or PHM. A cis- octahedral structure has been proposed for these complexes.  
Page(s): 867-870
Appears in Collections:IJC-A Vol.39A(08) [August 2000]

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