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IJC-A Vol.51A(11) [November 2012] >


Title: Effect of interaction between CuO and CeO2 on the performance of CuO-CeO2 catalysts for selective oxidation of CO in H2-rich streams
Authors: Zhu, Pengfei
Liu, Mei
Zhou, Renxian
Keywords: Catalysts
Ceria
Cupric oxide
Selective oxidation
Carbon monoxide oxidation
Oxidation
Issue Date: Nov-2012
Publisher: NISCAIR-CSIR, India
Abstract: A series of CuO–CeO2 catalysts have been prepared by different methods and the effects of interaction between CuO and CeO2 on the performance of CuO-CeO2 catalysts for selective oxidation of CO in H2-rich streams have been investigated. The results show that HY-CuO-CeO2 with strong interaction and synergistic effect between interfacial CuO and CeO2 exhibits superior catalytic activity, especially at low temperatures. For HY-CuO-CeO2, the temperature of 50 % CO conversion is only 75 °C and the temperature window of CO conversions up to 99.0 % is about 30 oC wide, from 120–140 °C. The strong interaction between copper and cerium oxide promotes the reduction of highly dispersed CuO species, the formation and stability of abundant Cu+ species and the production of abundant oxygen vacancies and lattice oxygen of copper oxide.
Page(s): 1529-1537
CC License:  CC Attribution-Noncommercial-No Derivative Works 2.5 India
ISSN: 0975-0975(Online); 0376-4710(Print)
Source:IJC-A Vol.51A(11) [November 2012]

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