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Title: CuII-exchanged montmorillonite K10 clay-catalyzed direct carboxylation of terminal alkynes with carbon dioxide
Authors: Aher, Ravindra D
Gade, Madhuri H
Reddy, R Santhosh
Sudalai, Arumugam
Keywords: Catalysts;Montmorillonite clays;Carboxylation;Carbon dioxide activation;Alkyne C-H activation;Alkyl esters
Issue Date: Sep-2012
Publisher: NISCAIR-CSIR, India
Abstract: A new, simple and straight-forward protocol for direct carboxylation of terminal alkynes has been developed using CuII-montmorillonite K10 clay as a heterogeneous catalyst and CO2 as the C1 carbon feedstock. Also coupling of terminal alkynes with CO2 (1 atm) in the presence of alkyl halides has been achieved under the same reaction conditions, thereby providing access to a variety of functionalized alkyl-2-alkynoates in high yields.
Page(s): 1325-1329
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.51A(09-10) [September-October 2012]

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