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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.51B [2012] >
IJC-B Vol.51B(09) [September 2012] >
| Title: | A simple and convenient chemoenzymatic approach for the synthesis of valuable triacylglycerol-based dendritic building blocks |
| Authors: | Gupta, Shilpi
Jalal, Sarah
Kumar, Sumit
Haag, Rainer
Sharma, Sunil K |
| Keywords: | Glycerol
Dendrimers
CAL-B
Chemoenzymatic
Regioselective |
| Issue Date: | Sep-2012 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Dendritic
macromolecules have a significant impact in the field of material sciences and
are one of the major starting points for nanotechnology as a result of the
numerous modifications that can be conducted, either on the surface or within
their molecular infrastructure. Thus taking advantage of their unique
architectural, structural, and functional features, a
highly efficient three-step convergent chemoenzymatic approach for the
synthesis of dendritic polyester/polyamido-ester building block structures
using structured triacylglycerols as acylating agent has been designed and
developed. This convergent approach is remarkable, because of the simplicity
and convenience to synthesize star shaped and linear dendritic building block
scaffolds, as it requires no purification other than a simple solvent
extraction. Different core molecules have been used to generate a series of
novel star shaped and linear dendritic building blocks without requiring any
chromatographic separation.
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| Page(s): | 1376-1387 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.51B(09) [September 2012]
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