Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/1461
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dc.contributor.authorShilmkar, T N-
dc.contributor.authorKolekar, S S-
dc.contributor.authorWadgaonkar, P P-
dc.contributor.authorAnuse, M A-
dc.date.accessioned2008-06-09T11:07:47Z-
dc.date.available2008-06-09T11:07:47Z-
dc.date.issued2008-05-
dc.identifier.issn0971–457X-
dc.identifier.urihttp://hdl.handle.net/123456789/1461-
dc.description291-297en_US
dc.description.abstractThe liquid-liquid extraction of indium(III) from sodium succinate media using n-octylaniline in toluene as an extractant was studied. Quantitative extraction of indium(III) was observed in the range of 0.004-0.0075 M sodium succinate at pH 3.8-6.0 with 4% n-octylaniline in toluene. Indium(III) was completely stripped from the metal loaded organic phase of the extractant with water and determined complexometrically. The stoichiometry of the extracted species was determined on the basis of slope analysis. The extraction was found to proceed by a ion-pair mechanism with the extracted species being [RNH₃⁺In(succinate)₂‾]org.Separation of indium(III) was carried out from some associated metals like Tl(I), Mg(II), Ni(II), Cu(II), Zn(II), Cd(II), Hg(II), Pb(II), Ge(IV), Sb(III), Bi(III). The selectivity of the extraction of indium(III) can also be achieved by use of a suitable masking agent for estimation and determination from the synthetic mixture corresponding to alloy to show the practical utility of the extractant.en_US
dc.language.isoen_USen_US
dc.publisherCSIRen_US
dc.sourceIJCT Vol.15(3) (May 2008)en_US
dc.subjectIndium(III)en_US
dc.subjectn-Octylanilineen_US
dc.subjectSolvent extractionen_US
dc.subjectSeparationen_US
dc.subjectSuccinateen_US
dc.titleRapid extraction and separation of indium(III) with a high molecular weight amineen_US
dc.typeArticleen_US
Appears in Collections:IJCT Vol.15(3) [May 2008]

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