|
NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR) >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Chemical Technology (IJCT) >
IJCT Vol.15 [2008] >
IJCT Vol.15(3) [May 2008] >
| Title: | An extended salt-effect model for organic solubility of water in a 5-100% tri-n-butyl phosphate/diluent/nitric acid/water biphasic system at 298.15 K |
| Authors: | Kumar, Shekhar Kumar, Rajnish Koganti, S B |
| Keywords: | Solubility PUREX process TBP Salt-effect Setschenow models |
| Issue Date: | May-2008 |
| Publisher: | CSIR |
| Abstract: | The solubility of water in the organic solutions, containing hydrocarbons, has traditionally been modeled by using empirical correlations. In this communication, an extended Setschenow model is proposed for predicting the organic solubility of water in a 5-100% tri-n-butyl phosphate/diluent-nitric acid-water biphasic system at 298.2 K. The literature data on water solubility were correlated to aqueous acid concentration and diluent concentration in the solvents. The proposed model was extended for temperature dependency of the solubility. |
| Page(s): | 287-290 |
| ISSN: | 0971–457X |
| Source: | IJCT Vol.15(3) [May 2008]
|
|