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IJC-B Vol.47B [2008] >
IJC-B Vol.47B(04) [April 2008] >

Title: A study on types of hydrogen bonding in crystal structure of 1-acetyl-3-thiosemicarbazide
Authors: Sireesha, B
Rao, B Krishna
Devi, Ch Sarala
Raghavaiah, Pallepogu
Keywords: Thiosemicarbazide
X-ray diffraction
Hydrated form
Issue Date: Apr-2008
Publisher: CSIR
Abstract: The unit cell structure of 1-acetyl-3-thiosemicarbazide (ATSC) and the types of hydrogen bonds present in crystalline form are envisaged from single crystal X-ray diffraction studies. The presence of four types of hydrogen bonds in crystal packing is evident (N─H• • •O, N─H• • •N, N─H• • •S and O─H• • •O) from the results obtained in present study. The topological analysis of hydrogen bonds indicated both inter- and intramolecular hydrogen bonding. Presence of water molecule is evident in its structure indicating that the title compound is in hydrated form. The single crystal X-ray diffraction data corresponding to hydrogen bonding reveals the hydrogen-bond strength sequence as: N─H• • •N > O─H• • •O > N─H• • •O > N─H• • •S.
Page(s): 592-596
ISSN: 0376-4699
Source:IJC-B Vol.47B(04) [April 2008]

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