|
NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR) >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.51B [2012] >
IJC-B Vol.51B(04) [April 2012] >
| Title: | Effects of phenols, amines and alcohols on the reactivity of triphenyltin hydride towards alkyl cinnamates |
| Authors: | Kalita, Pankaj
Choudhury, Diganta
Deka, Dibakar Chandra |
| Keywords: | Hydrostannation
Reduction
Alkyl Cinnamates
Tri¬phenyl¬tin Hydride |
| Issue Date: | Apr-2012 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | The reaction of alkyl
cinnamates with triphenyltin hydride under radical environment in the presence
of different phenols, amines and alcohols has been studied. In the presence of
phenols both reduced product and hydrostannated products are obtained, and the
selectivity between the two products depends on the reactivity of both the
phenol and the substrate, whereas in presence of alcohols and amines,
hydrostannated product is always the major in a mixture of both reduced and
hydrostannated products. |
| Page(s): | 646-649 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.51B(04) [April 2012]
|
|
