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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.51B [2012] >
IJC-B Vol.51B(01) [January 2012] >
| Title: | Mild, efficient and economical oxidative deprotection of allyl aryl ethers |
| Authors: | Lokhande, Pradeep D
Nawghare, Beena R |
| Keywords: | Allyl aryl ethers
Dimethyl sulphoxide
Oxidative deprotection |
| Issue Date: | Jan-2012 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | An efficient, economical
procedure for the cleavage of allyl aryl ethers using a catalytic amount of
iodine in dimethyl sulphoxide gives corresponding alcohols or phenols in high
yields under mild condition. The reaction can be performed in air without loss
of variety of oxidisable fuctional groups. Allyl ether of phenols is
selectively deprotected in preference to alcohols. The reaction is highly
regioselective and chemoselective. |
| Page(s): | 328-333 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.51B(01) [January 2012]
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