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Title: Europium triflate: An efficient, cost-effective and recyclable solid acid catalyst for highly chemoselective allylation of aldehydes
Authors: Kumbhare, Ravindra M
Sridhar, M
Keywords: Europium triflate;Allyltributylstannane;Aldehyde;Homoallylic alcohols
Issue Date: Dec-2011
Publisher: NISCAIR-CSIR, India
Abstract: Aldehydes undergo smooth nucleophilic addition with allyl-n-tributylstannane in the presence of europium triflate under extremely mild reaction conditions to afford the corresponding homoallylic alcohols in excellent yields with high chemoselectivity. The catalyst can be recovered by simple filtration and can be recycled in subsequent reactions.
Page(s): 1774-1778
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.50B(12) December 2011]

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