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IJPAP Vol.49(12) [December 2011] >


Title: Synthesis, characterization and CO2 gas sensing response of SnO2/Al2O3 double layer sensor
Authors: Waghuley, S A
Keywords: SnO2
Al2O3
Screen-printing technique
CO2 gas
Double layer sensor
Microstructure
Issue Date: Dec-2011
Publisher: NISCAIR-CSIR, India
Abstract: Tin dioxide (SnO2) material changes its properties depending on the ambient gas which can be utilized as gas sensing materials. Usually changes in electrical resistance/conductance in response to environmental gases are monitored. SnO2 and double layer (SnO2/Al2O3) sensors have been prepared by screen-printing technique on glass substrate. The sensors were used for different concentration (ppm) of CO2 gas investigation at different temperature. The sensing response (sensitivity) of SnO2/Al2O3 double layer sensor was found to be higher, compared with pure SnO2 sensor. The average grain size of SnO2 was determined from XRD pattern and found to be 120.7 nm. The activation energy (Ea) of first order reaction (n =1) for SnO2 has been found to be 72.06 kJ/g-mol from endo DDTA and 325.95 kJ/g-mol from exo DDTA. The microstructure of SnO2 has been studied from SEM analysis. The oxygen ions adsorb onto the surface of material removes electrons from the bulk and create a potential barrier that limits electron movement and resistivity. When exposed to an oxidizing gas such as CO2 then it is chemisorbed on bridging oxygen atoms with the formation of a surface carbonate, subsequently increasing the barrier height and resistivity.
Page(s): 816-819
CC License:  CC Attribution-Noncommercial-No Derivative Works 2.5 India
ISSN: 0975-1041 (Online); 0019-5596 (Print)
Source:IJPAP Vol.49(12) [December 2011]

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