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|Title:||Interaction of catechin with an iron(III) bis-benzimidazole diamide complex|
|Keywords:||Coordination chemistry;Iron;Benzimidazole diamides;Catechin;Electrochemical studies|
|Abstract:||Bis-benzimidazole diamide ligand, 3,3'-thiobis-(N-((1H-benzo[d]imidazol-2-yl)methyl) propanamide [GBTPA = L] has been synthesized and utilized to prepare new Fe(III) complexes with exogenous anionic ligands, Cl¯and NO3¯. The complexes have been characterized by IR, UV-visible, cyclic voltammetry, EPR and mass spectrometry. Low temperature EPR spectra are characteristic of a rhombic complex undergoing an axial distortion. Redox chemistry of catechin and iron(III) chloride complex in dimethyl sulfoxide, shows that catechin binds with Fe(III) complex leading to a considerable loss of antioxidant activity.|
|Appears in Collections:||IJC-A Vol.50A(12) [December 2011]|
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