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IJC-A Vol.50A(12) [December 2011] >


Title: Interaction of catechin with an iron(III) bis-benzimidazole diamide complex
Authors: Tyagi, Nidhi
Mathur, Pavan
Keywords: Coordination chemistry
Iron
Benzimidazole diamides
Catechin
Electrochemical studies
Issue Date: Dec-2011
Publisher: NISCAIR-CSIR, India
Abstract: Bis-benzimidazole diamide ligand, 3,3'-thiobis-(N-((1H-benzo[d]imidazol-2-yl)methyl) propanamide [GBTPA = L] has been synthesized and utilized to prepare new Fe(III) complexes with exogenous anionic ligands, Cl¯and NO¯. The complexes have been characterized by IR, UV-visible, cyclic voltammetry, EPR and mass spectrometry. Low temperature EPR spectra are characteristic of a rhombic complex undergoing an axial distortion. Redox chemistry of catechin and iron(III) chloride complex in dimethyl sulfoxide, shows that catechin binds with Fe(III) complex leading to a considerable loss of antioxidant activity.
Page(s): 1703-1708
CC License:  CC Attribution-Noncommercial-No Derivative Works 2.5 India
ISSN: 0975-0975(Online); 0376-4710(Print)
Source:IJC-A Vol.50A(12) [December 2011]

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