NISCAIR Online Periodicals Repository

NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR)  >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.50A [2011] >
IJC-A Vol.50A(11) [November 2011] >


Title: Synthesis of nano-MgO and identification of the destructive product of its reaction with 2-chloroethyl phenyl sulfide
Authors: Maddah, Bozorgmehr
Aminifar, Amir
Chalabi, Hossein
Keywords: Nanomaterials
Decontamination reaction
Magnesium oxide
Destructive adsorbent
Issue Date: Nov-2011
Publisher: NISCAIR-CSIR, India
Abstract: Nanocrystalline magnesium oxide has been prepared by the sol-gel method and characterized by X-ray diffraction, N2-BET, SEM and infrared spectroscopic techniques. Results confirm the formation of nano-MgO materials with crystallite size in the range of 5-20 nm and surface area of 336-556 m2/g. The product has been tested as destructive adsorbent for the decontamination of (2-chloroethyl) phenyl sulfide, a mimic of bis(2-chloroethyl) sulfide ("HD" or mustard gas). Destructive adsorbent reaction has been carried out in heptane and methanol media and investigated by GC-FID and GC-MS techniques. Reaction rate in heptane is observed to be higher than in methanol. It seems that a nonpolar media aids material transfer to the reactive surface sites without blocking these sites.
Page(s): 1587-1591
CC License:  CC Attribution-Noncommercial-No Derivative Works 2.5 India
ISSN: 0975-0975(Online); 0376-4710(Print)
Source:IJC-A Vol.50A(11) [November 2011]

Files in This Item:

File Description SizeFormat
IJCA 50A(11) 1587-1591.pdf149.13 kBAdobe PDFView/Open
 Current Page Visits: 735 
Recommend this item

 

National Knowledge Resources Consortium |  NISCAIR Website |  Contact us |  Feedback

Disclaimer: NISCAIR assumes no responsibility for the statements and opinions advanced by contributors. The editorial staff in its work of examining papers received for publication is helped, in an honorary capacity, by many distinguished engineers and scientists.

CC License Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India

Copyright © 2012 The Council of Scientific and Industrial Research, New Delhi. All rights reserved.

Powered by DSpace Copyright © 2002-2007 MIT and Hewlett-Packard | Compliant to OAI-PMH V 2.0

Home Page Total Visits: 586431 since 06-Feb-2009  Last updated on 18-Sep-2014Webmaster: nopr@niscair.res.in