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|Title:||Aminosilicate sol-gel embedded core-shell (TiO<sub>2</sub>-Au)<sub>nps</sub> nanomaterials modified electrode for the electrochemical detection of nitric oxide|
|Abstract:||A glassy carbon electrode modified with amine functionalized silicate sol-gel supported core-shell titanium dioxide–gold nanocomposite materials (EDAS/(TiO<sub>2</sub>-Au)<sub>nps</sub>) has been prepared and used as an electrochemical sensor for nitric oxide detection. The aminosilicate supported core-shell nanomaterials have been synthesized by the chemical reduction of HAuCl<sub>4</sub> and deposition of the formed Au<sub>nps</sub> on TiO<sub>2</sub> nanoparticles in the presence of N-[3-(trimethoxysilyl)propyl]-ethylene diamine as a support matrix and as a reducing agent. The so-prepared EDAS/(TiO<sub>2</sub>-Au)<sub>nps</sub> nanomaterials and the corresponding films have been characterized by spectral and electrochemical methods. A set of experimental conditions has been optimized for the fabrication of sensor electrode. The electrochemical properties of the GC/EDAS(TiO<sub>2</sub>-Au)<sub>nps</sub> modified electrode and the electrochemical detection of NO have been studied. The Osteryoung square wave voltammetric measurements reveals that the current response observed at the GC/EDAS(TiO<sub>2</sub>-Au)<sub>nps</sub> modified electrode for different concentrations of NO is linear with the lowest detection limit of 1 <img src='/image/spc_char/micro.gif' border=0><i style="">M</i>.|
|Appears in Collections:||IJC-A Vol.50A(09-10) [September-October 2011]|
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|IJCA 50A(09-10) 1388-1393.pdf||656.67 kB||Adobe PDF||View/Open|
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