|
NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR) >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.50B [2011] >
IJC-B Vol.50B(08) [August 2011] >
| Title: | Enantiospecific first total synthesis of cucumin-H |
| Authors: | Srikrishna, A
Dethe, Dattatraya H |
| Keywords: | Cucumanes
Triquinanes
Limonene
Nazarov cyclisation
Claisen rearrangement
Intramolecular cyclo¬propanation |
| Issue Date: | Aug-2011 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Enantiospecific first total synthesis of the
linear triquinane sesquiterpene cucumin-H has been described. (R)-Limonene has been employed as the
chiral starting material and a combination of Claisen rearrangement,
intramolecular cyclopropanation and Nazarov reactions are employed for the
regio- and stereospecific construction of the triquinane framework. |
| Page(s): | 1092-1106 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.50B(08) [August 2011]
|
|
