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Title: Enantiospecific first total synthesis of cucumin-H
Authors: Srikrishna, A
Dethe, Dattatraya H
Keywords: Cucumanes;Triquinanes;Limonene;Nazarov cyclisation;Claisen rearrangement;Intramolecular cyclo¬¨propanation
Issue Date: Aug-2011
Publisher: NISCAIR-CSIR, India
Abstract: Enantiospecific first total synthesis of the linear triquinane sesquiterpene cucumin-H has been described. (R)-Limonene has been employed as the chiral starting material and a combination of Claisen rearrangement, intramolecular cyclopropanation and Nazarov reactions are employed for the regio- and stereospecific construction of the triquinane framework.
Page(s): 1092-1106
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.50B(08) [August 2011]

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